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[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)

Author(s): Reza Takjoo | Seik Weng Ng | Edward R. T. Tiekink

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 7;
Start page: m944;
Date: 2012;
Original page

The MoVI atom in the title complex, [Mo(C11H13N3OS)O2(C2H6OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octahedral N2O4 donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N—H...O hydrogen bonds and eight-membered {...HNMoO}2 loops. The Schiff base ligand is disordered over two orientations of equal occupancy.

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