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(1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II)

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Author(s): Roji J. Kunnath | M. R. Prathapachandra Kurup | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 10;
Start page: m1302;
Date: 2012;
Original page

ABSTRACT
The CuII atom in the title compound, [Cu(NCS)2(C16H15N3O)], is bonded to the N atoms of two thiocyanate ions, and is N,N′-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu...O interaction. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio.

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