Academic Journals Database
Disseminating quality controlled scientific knowledge

1,3-Bis(4-tert-butylbenzyl)-4,5-dihydroimidazolium chloride monohydrate

ADD TO MY LIST
 
Author(s): Hakan Arslan | Don VanDerveer | Sedat Yaşar | smail Özdemir | Bekir Çetinkaya

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 65;
Issue: 2;
Start page: o310;
Date: 2009;
Original page

ABSTRACT
In the title compound, C25H35N2+·Cl−·H2O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N—C—N carbon and the opposite C—C bond. The N—C—N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714 (8) and 0.286 (8). In the crystal, O—H...Cl and C—H...O hydrogen bonds help to establish the packing.
Affiliate Program     

Tango Jona
Tangokurs Rapperswil-Jona