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1,3-Bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium trichlorido(η6-p-cymene)ruthenate(II)

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Author(s): Hakan Arslan | Don VanDerveer | smail Özdemir | Nevin Gürbüz | Yetkin Gök | Bekir Çetinkaya

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 65;
Issue: 1;
Start page: m111;
Date: 2009;
Original page

ABSTRACT
The asymmetric unit of the title compound, (C14H17N2S2)[Ru(C10H14)Cl3], contains a 1,3-bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium cation and a trichlorido(η6-p-cymene)ruthenate(II) anion. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three chloride atoms occupying the other three sites. The N—C bond lengths of the N—C—N unit of the pyrimidinium cation are shorter than the average single C—N bond length of 1.48 Å, thus showing double-bond character, indicating a partial electron delocalization within the N—C—N fragment. The pyrimidine ring has an envelope conformation. Four intermolecular C—H...Cl hydrogen bonds generate a three-dimensional hydrogen-bonded framework.
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Tango Jona
Tangokurs Rapperswil-Jona