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{2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ2N1,O]-5-methoxyphenolato-κO1}chloridocopper(II)

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Author(s): Roji J. Kunnath | M. R. Prathapachandra Kurup | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 9;
Start page: m1194;
Date: 2012;
Original page

ABSTRACT
The asymmetric unit of the title compound, [Cu(C9H10N3O3)Cl], contains two independent molecules with similar structures. The CuII cation is N,O,O′-chelated by the deprotonated Schiff base ligand and is further coordinated by a Cl− anion in a distorted ClNO2 square-planar geometry. In the crystal, adjacent molecules are linked by N—H...O and N—H...Cl hydrogen bonds, forming a two-dimensional network parallel to [100].
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