Academic Journals Database
Disseminating quality controlled scientific knowledge

(2E)-2-(Thiophen-2-ylmethylidene)-1,2,3,4-tetrahydronaphthalen-1-one

ADD TO MY LIST
 
Author(s): Abdullah M. Asiri | Hassan M. Faidallah | Khalid A. Alamry | Seik Weng Ng | Edward R. T. Tiekink

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 7;
Start page: o2298;
Date: 2012;
Original page

ABSTRACT
In the title compound, C15H12OS, the cyclohexene ring has a twisted boat conformation with the C atom between the ketone and methylene atom and this methylene C atom lying 0.280 (3) and 0.760 (3) Å, respectively, from the plane through the remaining four atoms (r.m.s. deviation = 0.004 Å). The dihedral angle between the benzene and thiophene rings [21.64 (9)°] indicates an overall twist in the molecule. The thiophene S and ketone O atoms are anti, an orientation that allows the close approach of these atoms [3.3116 (17) Å] in the crystal structure and which leads to the formation of helical supramolecular chains along the c axis.
Save time & money - Smart Internet Solutions     

Tango Rapperswil
Tango Rapperswil