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4-Bromo-N-(4-hydroxybenzylidene)aniline

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Author(s): L. Jothi | G. Vasuki | R. Ramesh Babu | K. Ramamurthi

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 3;
Start page: o772;
Date: 2012;
Original page

ABSTRACT
In the title compound, C13H10BrNO, the benzene ring planes are inclined at an angle of 48.85 (17)°, resulting in a nonplanar molecule. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the HC=N plane. In this case, the HC=N unit makes dihedral angles of 11.1 (4) and 38.5 (3)° with the hydroxybenzene and bromobenzene rings, respectively. In the crystal, the molecules are linked by O—H...N hydrogen bonds to form infinite (C8) chains along the b axis.
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