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(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine

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Author(s): Chennan Ramalingan | Seik Weng Ng | Edward R. T. Tiekink

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 7;
Start page: o2267;
Date: 2012;
Original page

ABSTRACT
In the title compound, C26H27BrN2O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bisectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromobenzene ring. The latter is coplanar with the methoxy(methylidene)amine fragment [N—O—C—C torsion angle = −171.7 (2)°]. Linear supramolecular chains, approximately along [112], sustained by C—H...π interactions, feature in the crystal packing.
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