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Ammonium diamminesilver(I) bis(5-chloro-2-hydroxybenzenesulfonate) trihydrate

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Author(s): Zhao-Peng Deng | Shan Gao | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 2;
Start page: m225;
Date: 2012;
Original page

ABSTRACT
The reaction of silver nitrate with 5-chloro-2-hydroxybenzenesulfonic acid in the presence of ammonia yielded the title salt, (NH4)[Ag(NH3)2](C6H4ClO4S)2·3H2O. The AgI ion shows linear coordination [N—Ag—N = 175.2 (1) °]. The ammonium and diamminesilver cations, the benzenesulfonate anion and the lattice water molecules interact through an intricate network of N—H...O and O—H...O hydrogen bonds to form a three-dimensional network.

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