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Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ4O1,N,N′,O1′}cobalt(III) acetonitrile monosolvate

Author(s): Yang Lin | Guang-Ming Li | Peng Chen | Peng-Fei Yan | Guang-Feng Hou

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 67;
Issue: 8;
Start page: m1162;
Date: 2011;
Original page

In the title complex, [Co(C22H18N2O4)(CN)(H2O)]·CH3CN, the CoIII ion is six-coordinated in a distorted octahedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water molecule and one C atom from a cyanide group at the axial positions. O—H...O hydrogen bonds connect adjacent complex molecules into dimers. C—H...N hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distances = 3.700 (2) and 3.845 (2) Å] are also present.
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