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Aqueous Solution Preparation, Structure, and Magnetic Properties of Nano-Granular ZnxFe3−xO4 Ferrite Films

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Author(s): Tian Qiang | Wang Qian | Xie Qingshui | Li Jiangong

Journal: Nanoscale Research Letters
ISSN 1931-7573

Volume: 5;
Issue: 9;
Start page: 1518;
Date: 2010;
Original page

Keywords: Ferrite films | Aqueous solution deposition | Nano-granules | Magnetic properties

ABSTRACT
Abstract This paper reports a simple and novel process for preparing nano-granular ZnxFe3−xO4 ferrite films (0 ≤ x ≤ 0.99) on Ag-coated glass substrates in DMAB-Fe(NO3)3-Zn(NO3)2 solutions. The deposition process may be applied in preparing other cations-doped spinel ferrite films. The Zn content x in the ZnxFe3−xO4 films depends linearly on the Zn2+ ion concentration ranging from 0.0 to 1.0 mM in the aqueous solutions. With x increasing from 0 to 0.99, the lattice constant increases from 0.8399 to 0.8464 nm; and the microstructure of the films changes from the non-uniform nano-granules to the fine and uniform nano-granules of 50–60 nm in size. The saturation magnetization of the films first increases from 75 emu/g to the maximum 108 emu/g with x increasing from 0 to 0.33 and then decreases monotonously to 5 emu/g with x increasing from 0.33 to 0.99. Meanwhile, the coercive force decreases monotonously from 116 to 13 Oe.

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