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Bis[μ-(E)-N-(pyridin-3-ylmethylidene)hydroxyamine]-κ2N1:N3;κ2N3:N1-bis{[(E)-N-(pyridin-3-ylmethylidene-κN)hydroxyamine]silver(I)} dinitrate

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Author(s): Shan Gao | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 12;
Start page: m1547;
Date: 2012;
Original page

ABSTRACT
In the centrosymmetric dinuclear title AgI compound, [Ag2(C6H6N2O)4](NO3)2, the aromatic amine-coordinated AgI atom is further bridged by two hydroxylamine molecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound molecules via O—H...O hydrogen bonds, generating a chain running along the a-axis direction.
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