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Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ2N,N′}urea-κO)nickel(II) dinitrate

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Author(s): N. Aiswarya | Jinsa Mary Jacob | M. R. Prathapachandra Kurup | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 7;
Start page: m918;
Date: 2012;
Original page

ABSTRACT
The NiII atom in the title salt, [Ni(C19H16N4O)2](NO3)2, is N,N′,O-chelated by two neutral Schiff base ligands in a distorted octahedral geometry. One nitrate ion interacts with the metal atom indirectly, in an outer-sphere type of coordination, through N—H...O hydrogen bonds; the other nitrate ion does not engage in any interactions and is equally disordered over two positions in the crystal.

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