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Bis(4-methyl-N-{(2Z,4E)-4-[(4-methylphenyl)imino]pent-2-en-2-yl}anilinido)zinc

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Author(s): Benjamin A. Vaughan | Anthony E. Wetherby | Rory Waterman

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 3;
Start page: m343;
Date: 2012;
Original page

ABSTRACT
The title compound, [Zn(C19H21N2)2], appears to be the first example of a zinc complex supported by two β-diketiminate (nacnac) ligands. This complex crystallizes with a distorted tetrahedrally coordinated ZnII atom that diposes the two nacnac ligands approximately orthogonally to one another [angle between the two N—Zn—N mean planes is 89.91 (10)°], with average Zn—N bond lengths of 1.992 (4) Å.
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