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Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ2O1,O2)cobaltate(II) dihydrate: an ion-pair complex

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Author(s): Papa Aly Gaye | Adama Sy | Ibrahima Elhadj Thiam | Mohamed Gaye | Pascal Retailleau

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 67;
Issue: 9;
Start page: m1269;
Date: 2011;
Original page

ABSTRACT
The CoII ion in the title complex, (C4H14N2)2[Co(C2O4)3]·2H2O, is coordinated by three oxalate ions, resulting in a distorted octahedral geometry. Two uncoordinated water molecules are present in asymmetric unit. Intermolecular N—H...O and O—H...O hydrogen bonds between the different entities stabilize the crystal structure.
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