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Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)methylidene]dithiocarbazato}zinc acetonitrile monosolvate

Author(s): Thahira B. S. A. Ravoof | Siti Aminah Omar | Mohamed Ibrahim Mohamed Tahir | Karen A. Crouse

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 4;
Start page: m390;
Date: 2012;
Original page

In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H...N hydrogen-bonding interactions.
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