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catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]

Author(s): Noriaki Ozaki | Ryo Yamada | Koji Nakabayashi | Shin-ichi Ohkoshi

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 67;
Issue: 6;
Start page: m702;
Date: 2011;
Original page

The polymeric title compound, {[MnII2WIV(CN)8(C10H8N2)2(H2O)4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinate distorted octahedral. Two pairs of CN ligands of W(CN)8 are bridged to two MnII atoms, the remaining CN ligands being terminal. Each MnII atom is additionally coordinated by a bidentate 2,2′-bipyridyl ligand and two water molecules. The crystal structure is stabilized by O—H...O and O—H...N hydrogen bonds.
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