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catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ2N1:N4)aminomethyl]phenol] nitrate]

Author(s): Zhao-Peng Deng | Shan Gao | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 9;
Start page: m1171;
Date: 2012;
Original page

The AgI atom in the polycationic salt, {[Ag(C11H11N3O)]NO3}n, shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO3− counter-ions surround the polymeric chain and interact only weakly with it [Ag...O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O—H...O and N—H...O hydrogen bonds.
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