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Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex

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Author(s): Gun Binzet | Ulrich Flörke | Nevzat Külcü | Hakan Arslan

Journal: European Journal of Chemistry
ISSN 2153-2249

Volume: 3;
Issue: 2;
Start page: 211;
Date: 2012;
Original page

Keywords: Thiourea | Benzamide | Copper complex | Benzoylthiourea | Crystal structure | Single crystal X‐ray diffraction

ABSTRACT
The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido)copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o, Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.
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