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Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex

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Author(s): Gun Binzet | Ulrich Flörke | Nevzat Külcü | Hakan Arslan

Journal: European Journal of Chemistry
ISSN 2153-2249

Volume: 3;
Issue: 1;
Start page: 37;
Date: 2012;
Original page

Keywords: Thiourea | Benzamide | Nickel complex | Benzoylthiourea | Crystal structure | Single crystal X‐ray diffraction

ABSTRACT
We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3.  In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

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