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Dichlorido(1-{(E)-[phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate

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Author(s): Roji J. Kunnath | M.R. Prathapachandra Kurup | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 9;
Start page: m1181;
Date: 2012;
Original page

ABSTRACT
The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R42(8) association.
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