Academic Journals Database
Disseminating quality controlled scientific knowledge

Dichlorido{2-[(E)-phenyl(pyridin-2-yl-κN)methylidene]-N-phenylhydrazinecarboxamide-κ2N2,O}copper(II)

ADD TO MY LIST
 
Author(s): N. Aiswarya | M. Sithambaresan | M. R. Prathapachandra Kurup | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 69;
Issue: 11;
Start page: m588;
Date: 2013;
Original page

ABSTRACT
The title compound, [CuCl2(C19H16N4O)], contains a CuII atom N,N′,O-chelated by a neutral N-phenylhydrazinecarboxamide ligand and additionally coordinated by two Cl atoms, resulting in a distorted square-pyramidal geometry. The ligating atoms in the basal square plane of the complex comprise the azomethine N, the pyridine N, the amide O and one of the Cl atoms, whereas the other Cl atom occupies an apical position. The apical Cl atoms in adjacent layers function as hydrogen-bond acceptors to both NH groups. Intermolecular C—H...Cl and C—H...O interactions are also observed.
Save time & money - Smart Internet Solutions     

Tango Jona
Tangokurs Rapperswil-Jona