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Dimethylbis(2-methylquinolin-8-olato-κ2N,O)tin(IV)

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Author(s): Ezzatollah Najafi | Mostafa M. Amini | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 12;
Start page: m1551;
Date: 2012;
Original page

ABSTRACT
The SnIV cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methylquinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the molecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyltin skeleton [C—Sn—C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak intermolecular C—H...O hydrogen bonding occurs in the crystal.
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