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The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ2C,N}(ferrocene-1,1′-diyl)gallium(III)

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Author(s): Jörg A. Schachner | J. Wilson Quail | Jens Müller

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 64;
Issue: 4;
Start page: m517;
Date: 2008;
Original page

ABSTRACT
The title compound, [GaFe(C5H4)2(C14H28NSi3)] or [{(2-H4C5N)Me2Si}(Me3Si)2C]Ga(C5H4)2Fe, a galla[1]ferrocenophane, crystallizes with two independent molecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands are 15.4 (2) and 16.4 (2)°, with gallium in a distorted tetrahedral coordination environment.

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