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HOMO AND HETEROPOLYNUCLEAR NEW OXALATOORGANOTIN (IV) ADDUCTS. AN INFRARED AND MÖSSBAUER STUDY

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Author(s): Hayat Qamar-Kane | Libasse Diop

Journal: Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry
ISSN 1582-540X

Volume: 12;
Issue: 3;
Start page: 249;
Date: 2011;
Original page

Keywords: homo- and heteropolynuclear adducts | infrared | mono- and bichelating oxalate

ABSTRACT
Six new oxalato homo (Sn only) and hetero (Sn, Cd, Sb) polynuclear adducts have been obtained on allowing (Me4N)2(C2O4)∙2H2O to react with SnPh2Cl2 or (Me4N)2(C2O4)SnPh2∙H2O to react with SnPh2Cl2, SnMe2Cl2, CdCl2, CdBr2∙4H2O or SbCl3 in specific ratio. The obtained adducts have been studied by elemental analyses and infrared spectroscopy and structures suggested on the basis of the spectroscopic data.
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