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(Me4N)2SO4•4SnPh3NCS AND (Me2N)2CO•4SnPh3Cl - SYNTHESIS AND SPECTROSCOPIC STUDIES

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Author(s): Kochikpa A. Y. Okio | Libasse Diop

Journal: Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry
ISSN 1582-540X

Volume: 11;
Issue: 4;
Start page: 479;
Date: 2010;
Original page

Keywords: tetracoordinating sulphate and tetramethyl NN’ urea | tetranuclear adducts | trans coordinated SnPh3 residue | Mössbauer | IR

ABSTRACT
Two tetranuclear SnPh3 residue containing adducts have been synthesized and characterized by infrared and Mössbauer spectroscopies. The structure are both discrete, the sulphate anion and the tetramethyl NN’ urea (TMU) acting as tetracoordinating ligands, the environment around the tin IV centres being trans trigonal bipyramidal.
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