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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis[O,O′-bis(4-methylphenyl) thiophosphate]

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Author(s): Yang-Guang Xiang | Bin Xie | Li-Ke Zou | Jian-Shen Feng | Chuan Lai

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 67;
Issue: 1;
Start page: m59;
Date: 2011;
Original page

ABSTRACT
In the centrosymmetric title complex, [Ni(C16H36N4)](C14H14O3PS)2, the NiII ion is coordinated by four N atoms and two O atoms within a slightly distorted NiN4O2 octahedral geometry. The asymmetric unit consits of one NiII ion that is located on a center of inversion, half of the macrocylic ligand and one anion occupying general positions. Intramolecular N—H...O and N—H...S hydrogen bonding is found between the macrocyclic ligand and the monothiophosphate anion.

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