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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis[O,O′-bis(4-methylphenyl) thiophosphate]

Author(s): Yang-Guang Xiang | Bin Xie | Li-Ke Zou | Jian-Shen Feng | Chuan Lai

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 67;
Issue: 1;
Start page: m59;
Date: 2011;
Original page

In the centrosymmetric title complex, [Ni(C16H36N4)](C14H14O3PS)2, the NiII ion is coordinated by four N atoms and two O atoms within a slightly distorted NiN4O2 octahedral geometry. The asymmetric unit consits of one NiII ion that is located on a center of inversion, half of the macrocylic ligand and one anion occupying general positions. Intramolecular N—H...O and N—H...S hydrogen bonding is found between the macrocyclic ligand and the monothiophosphate anion.

Tango Jona
Tangokurs Rapperswil-Jona

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