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(meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate]

Author(s): Bin Xie | Yang-Guang Xiang | Li-Ke Zou | Xiu-Li Chang | Chang-You Ji

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 65;
Issue: 9;
Start page: m1053;
Date: 2009;
Original page

In the title compound, [Ni(C16H32N4)](C14H14O2PS2)2 or [Ni(trans[14]dien)][S2P(OC6H4Me-4)2]2, where trans[14]dien is meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene, the NiII ion lies across a centre of inversion and is four-coordinated in a relatively undistorted square-planar arrangement by the four N atoms of the macrocyclic ligand trans[14]dien. The two O,O′-di(4-methylphenyl)dithiophosphates act as counter-ions to balance the charge. Important geometric data include Ni—N = 1.9135 (16) and 1.9364 (15) Å.

Tango Jona
Tangokurs Rapperswil-Jona

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