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Nanocomposite Material Based on GaSe and InSe Layered Crystals Intercalated by RbNO3 Ferroelectric

Author(s): Z.R. Kudrynskyi | V.V. Netyaga

Journal: Journal of Nano- and Electronic Physics
ISSN 2077-6772

Volume: 5;
Issue: 3;
Start page: 03028-1;
Date: 2013;
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Keywords: Nanocomposite materials | Layered crystals | Ferroelectric | Intercalation | Gallium selenide | Indium selenid

In the present study, we established for the first time that single-crystal samples of gallium GaSe and indium InSe selenides can be intercalated by molecules of RbNO3 ferroelectric salt rubidium nitrate. We investigated kinetics of the intercalation process at different temperature-time regimes. Structural properties of the intercalate nanocomposites were studied by X-ray diffraction. The studied structures can be presented as composite superlattices which consist of a lattice of anisotropic layered semiconductor with embedded ferroelectric layers. We established that GaSe nanocomposite material exhibits electric energy storage properties. Energy storage properties are associated with polarization of the intercalated ferroelectric under external electric field. We developed a solid state electric energy storage device on the basis of GaSe nanocomposite material.
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