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NEW MX2 OXALATO POLYNUCLEAR ADDUCTS (M = Cd, Hg, Zn; X = Cl, Br): SYNTHESIS AND INFRARED STUDY

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Author(s): Hayat Qamar-Kane | Alioune Fall | Libasse Diop

Journal: Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry
ISSN 1582-540X

Volume: 12;
Issue: 4;
Start page: 357;
Date: 2011;
Original page

Keywords: cage | ionic structures | polychelating oxalate

ABSTRACT
Nine mono-, di- and trinuclear MX2 oxalato adducts have been synthesized, their infrared study carried out. The suggested structures are ionic, the oxalate anion behaving as a chelating ligand. Cage structures, when non symmetrical cations are involved,have been suggested.
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