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NEW ORGANOTIN (IV) HETEROPOLYNUCLEAR COMPLEXES CONTAINING [SnPh[sub]2[/sub]Cl[sub]2[/sub]X][sub][sup]- [/sup][/sub](X = Cl, Br): SYNTHESIS AND SPECTROSCOPIC STUDIES

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Author(s): Seydi Mansour Sy Seck | Libasse Diop | Samuel Jouen | Béatrice Hannoyer

Journal: Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry
ISSN 1582-540X

Volume: 11;
Issue: 2;
Start page: 303;
Date: 2010;
Original page

Keywords: mono- | bi- | trinuclear [SnPh2Cl2X]- | infrared | Mössbauer | discrete structures

ABSTRACT
Four [SnPh[sub]2[/sub]Cl[sub]2[/sub]X][sup]-[/sup] (X = Cl, Br) containing complexes with metal complexes adverse cations have been synthesized and studied by infrared and Mössbauer spectroscopy. The suggested structures are ionic, SnPh[sub]2[/sub]Cl[sub]2[/sub]X[sup]-[/sup] as mononuclear, a binuclear or a trinuclear anion being in electrostatic interactions with the metal complex cation.
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