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NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES

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Author(s): Kochikpa Y.A. Okio | Libasse Diop

Journal: Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry
ISSN 1582-540X

Volume: 11;
Issue: 2;
Start page: 299;
Date: 2010;
Original page

Keywords: phenyl tin compound | benzoate | infrared spectrum | Mössbauer spectrum | polymeric structure

ABSTRACT
On allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahedral, PhCO2- behaving as a monocoordinating ligand.
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