Academic Journals Database
Disseminating quality controlled scientific knowledge

Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere

ADD TO MY LIST
 
Author(s): JOSEF HUSAREK | RICHARD PASTOREK | MICHAL MALON | ZDENEK SINDALAR | MAREK PAVLICEK

Journal: Journal of the Serbian Chemical Society
ISSN 0352-5139

Volume: 69;
Issue: 12;
Start page: 1053;
Date: 2004;
VIEW PDF   PDF DOWNLOAD PDF   Download PDF Original page

Keywords: nickel(II) cyclohexylethyldithiocarbamate complexes | monodantate P-donor ligands | synthesis | 31P{1H}-NMR spectroscopy

ABSTRACT
A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)] (X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis, magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes, with a square-planar NiS2PX chromophore.
Affiliate Program     

Tango Jona
Tangokurs Rapperswil-Jona