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Poly[[pentaaqua(μ4-pyridine-2,4,6-tricarboxylato)(μ3-pyridine-2,4,6-tricarboxylato)disamarium(III)] monohydrate]

Author(s): Yong-Wei Jin | Hong-lin Zhu

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 3;
Start page: m287;
Date: 2012;
Original page

The asymmetric unit of the title compound, {[Sm2(C8H2NO6)2(H2O)5]·H2O}n, contains two independent SmIII ions, two pyridine-2,4,6-tricarboxylate (ptc) ligands, five aqua ligands and one lattice water molecule. One SmIII ion is nine-coordinated by one N and five O atoms from the three ptc ligands and three aqua ligands in a distorted monocapped square antiprismatic geometry, and the other is eight-coordinated by one N and five O atoms from three ptc ligands and two aqua ligands in a 4,4′-bicapped trigonal antiprismatic geometry. The ptc ligands brigde the SmIII ions into a three-dimensional polymeric framework. Extensive O—H...O hydrogen bonding is observed in the crystal structure.

Tango Jona
Tangokurs Rapperswil-Jona

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