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Preparation and characterization of novel oxo-centered basic p-chlorobenzoic bridging trinuclear complexes

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Author(s): IMAN KHOSRAVI | MOHAMMAD YAZDANBAKHSH

Journal: Journal of the Serbian Chemical Society
ISSN 0352-5139

Volume: 75;
Issue: 7;
Start page: 929;
Date: 2010;
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Keywords: mixed-valence | oxo-centered | trinuclear complexes | spectroscopy | carboxylic ligand | IR spectra

ABSTRACT
Three new oxo-centered trinuclear complexes, one of them a mixed-valence complex [Mn3O(C7H4O2Cl)6(Py)3]Py (1) and the others, mixed-metal complexes of [Fe2MnO(C7H4O2Cl)6(Py)3]NO3 (2) and [Fe2CoO(C7H4O2Cl)6(Py)3] (3) were synthesized by the direct reaction between metal nitrates and p-chlorobenzoic acid. These complexes were characterized by elemental analyses (CHN), atomic absorption spectroscopy and spectral (IR, electronic) studies. These are new type of oxo-bridged mixed-metal complexes in which the carboxylate ligand is p-chlorobenzoic acid. The UV spectra of the complexes exhibited a strong band in the region 42,500 cm-1 which is related to the (π → π*) transitions of the pyridine ligand. The IR spectra of these compounds showed two strong stretching vibrations bands, indicating a bridging coordination mode of the carboxylic group of the ligand in the complexes.
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