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{S-Benzyl 3-[(6-methylpyridin-2-yl-κN)methylidene]dithiocarbazato-κ2N3,S}zinc

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Author(s): Thahira B. S. A. Ravoof | Siti Aminah Omar | Mohamed Ibrahim Mohamed Tahir | Karen A. Crouse

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 5;
Start page: m534;
Date: 2012;
Original page

ABSTRACT
The title compound, [Zn(C15H14N3S2)2], contains two chemically equivalent Schiff base anions that are coordinated to the ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 75.40 (6)° and the widest angle being 162.87 (6)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 85.65 (5)°. Weak C—H...S hydrogen bonds are also observed.
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