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Syntheses and Crystal Structures of [Cu3{μ-(NSPh2)2N}2Cl2] and [Cu3{μ-(NSPh2)2N}2{(NSPh2)2N}2]Cl2

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Author(s): Takayoshi Fujii | Mihoko Kanno | Mitsuo Hirata

Journal: International Journal of Inorganic Chemistry
ISSN 2090-2026

Volume: 2010;
Date: 2010;
Original page

ABSTRACT
We have prepared the trinuclear complexes [Cu3{μ-(NSPh2)2N}2Cl2] (3) and [Cu3{μ-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 1− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.
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