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Synthesis and Magnetic Properties of the Novel Dithiadiazolyl Radical, p-NCC6F4C6F4CNSSN

Author(s): Antonio Alberola | Robert J. Less | Fernando Palacio | Christopher M. Pask | Jeremy M. Rawson

Journal: Molecules
ISSN 1420-3049

Volume: 9;
Issue: 9;
Start page: 771;
Date: 2004;
Original page

Keywords: Magnetic properties | dithiadiazolyl | molecular magnetism | organic magnet.

The dithiadiazolyl radical p-NCC6F4C6F4CNSSN• (4) retains its monomericnature in the solid state with molecules linked together into chains via supramolecularCN···S interactions. Variable temperature magnetic studies on 4 show that it behaves as anear-ideal Curie paramagnet (|θ| less than 0.1 K), indicating negligible intermolecularexchange. The effective magnetic moment (1.78 μB) is temperature independent and inexcellent agreement with the value expected for an S = 1⁄2 paramagnet with g = 2.01(1.74μB). The lack of exchange coupling between radicals is attributed to the absence ofsignificant orbital overlap between radical centres.
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