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Synthesis of New Zn-containing Derivative by Multi-step Ion-exchanges

Author(s): CHEN Yu-Feng, ZHOU Song-Hua, YANG Xiao-Jing

Journal: Journal of Inorganic Materials
ISSN 1000-324X

Volume: 25;
Issue: 8;
Start page: 806;
Date: 2010;
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Keywords: SrBi2Nb2O9; protonation; ion-exchange; UV-Vis absorption

A new material, Zn-containing derivative from SrBi2Nb2O9, was synthesized by multi-step ion-exchanges with H+/(BiO)+, TMA+ (tetramethylammonium ions)/H+, and Zn(NH3)42+/TMA+ step by step. X-ray diffraction (XRD) patterns exhibite the difference in the layered structures among the precursor SrBi2Nb2O9 (SBN), its protonated product (HSN), and Zn-containing derivative (ZSN). The compositional analyses reveal the extraction of most of the bismuth atoms and the loss of a small part of the strontium atoms after protonation. The UV-Vis (ultraviolet-visible) absorption edge of the Zn-containing derivative shifts markedly to high energy compared with that of the precursor and its protonated product.

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