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Tris{2-[(pyrimidin-2-yl-κN)aminomethyl]phenol}silver(I) nitrate

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Author(s): Shan Gao | Seik Weng Ng

Journal: Acta Crystallographica Section E
ISSN 1600-5368

Volume: 68;
Issue: 12;
Start page: m1543;
Date: 2012;
Original page

ABSTRACT
The AgI atom in the title compound, [Ag(C11H11N3O)3]NO3, shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak Ag...Onitrate interactions [Ag...O = 2.691 (5) and 3.073 (5) Å]. The cation and anion are linked by O—H...N and N—H...O hydrogen bonds, generating a three-dimensional network.
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