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The wide synthetic versatility of five membered rings containing phosphorus

Author(s): Caliman Vinicius

Journal: QuĂ­mica Nova
ISSN 0100-4042

Volume: 23;
Issue: 3;
Start page: 346;
Date: 2000;
Original page

Keywords: cyclopentadiene containing phosphorus | organophosphorus | coordination compounds

The chemistry of cyclopentadiene rings has been widely studied. This review article deals with a similar chemistry of new compounds containing from 1 to 5 phosphorus atoms on the ring substituting the carbon atoms. The neutral rings containing one, two and three phosphorus atoms can be used as building blocks for the synthesis of new organic compounds containing phosphorus. These rings plus the anionic ones also show great potential as ligands in coordination chemistry. The aim of this article is to show how important this new area is and how diverse the chemistry related to a single type of ring can be.

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