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Fluorinated and Non-Fluorinated Electro-Optic Copolymers: Determination of the Time and Temperature Stability of the Induced Electro-Optic Coefficient

Author(s): Alessandro Belardini

Journal: Applied Sciences
ISSN 2076-3417

Volume: 2;
Issue: 4;
Start page: 682;
Date: 2012;
Original page

Keywords: electro-optic polymers | fluorinated polymers | electro-optic time stability

Organic fluorinated materials demonstrate their excellent electro-optic properties and versatility for technological applications. The partial substitution of hydrogen with fluorine in carbon-halides bounds allows the reduction of absorption losses at the telecommunication wavelengths. In these interesting compounds, the electro-optic coefficient was typically induced by a poling procedure. The magnitude and the time stability of the coefficient is an important issue to be investigated in order to compare copolymer species. Here, a review of different measurement techniques (such as nonlinear ellipsometry, second harmonic generation, temperature scanning and isothermal relaxation) was shown and applied to a variety of fluorinated and non-fluorinated electro-optic compounds.
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