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Mannich-Type Reactions of Aldimines and Hetero Diels-Alder Reactions of Aldehydes Catalyzed by Anion-Type Lewis Bases Derived from a Single Molecule

Author(s): Kaori Ishimaru | Daiki Maeda | Kaori Ono | Yuya Tanimura

Journal: International Journal of Organic Chemistry
ISSN 2161-4687

Volume: 02;
Issue: 03;
Start page: 188;
Date: 2012;
Original page

Keywords: Anion Catalyst | Lewis Base | Proline | Mannich-Type Reaction | Hetero Diels-Alder Reaction

Mannich-type reactions of aldimines with silyl enolates and hetero Diels-Alder reactions of aldehydes with Danishef-sky’s diene in the presence of anion catalysts derived from proline were performed to afford the corresponding products in high yields.
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