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Mass Transfer and Reaction Kinetics of PH3 Absorption with Pd(Ⅱ)-Cu(Ⅱ) in Double-Stirred Cell

Author(s): Guangfei Qu | Yixing Ma | Junyan Li | Yilu Lin | Ping Ning

Journal: Scientific Journal of Frontier Chemical Development
ISSN 2167-163X

Volume: 3;
Issue: 2;
Start page: 30;
Date: 2013;
Original page

Keywords: Posphine | Catalytic Oxidation | Kinetics

The solution of Pd(Ⅱ)-Cu(Ⅱ) was used as a self-screened catalyst of liquid phase catalytic oxidation to remove phosphine. Mass transfer and reaction kinetics were studied in a double-stirred cell. The results indicated that the system was an interfacial instantaneous reaction. Gas-side and liquid-side mass transfer coefficient were 3.88×10-7 mol?(m2?Pa?s)-1 and 6.74×10-7 mol?(m2?Pa?s)-1 (303.15 K) respectively. The rate constants of the first-order reaction were over the order of 105 under the experiment temperatures. Ha number was 552.56, and practical enhancement factor was 593.63.
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