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SYNTHESIS OF 3-CARBOXYCOUMARINS USING PHASE TRANSFER CATALYSIS Synthese von 3-CARBOXYCOUMARINS VERWENDUNG Phasentransferkatalyse

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Author(s): M.S Lambaa , J.K Makrandib and Suresh Kumar

Journal: Heterocyclic Letters
ISSN 2231-3087

Volume: 3;
Issue: 2;
Start page: 177;
Date: 2013;
Original page

Keywords: 3-Carboxycoumarins | ethylcoumarin-3-carboxylate | phase transfer catalysis | salicylaldehyde | diethylmalonate

ABSTRACT
The condensation of suitably substituted salicylaldehydes with diethylmalonate in biphase medium using phase transfer catalyst results in to the formation of ethylcoumarin-3-carboxylates. Ethylcoumarin-3-carboxylates so formed on hydrolysis gives coumarin-3-carboxylic acid in high yield.

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